青海湖地区生物中正构烷烃及其氢同位素组成与影响因素     

段毅  吴应忠  吴保祥  孙涛 《地质学报》2018,92(7):1541-1550

青海湖是我国最大的内陆咸水湖泊。本文应用GC-MS和GC-TC-IRMS同位素分析技术,对青海湖水生生物和周围地区陆生生物中正构烷烃及其氢同位素进行了分析,研究了生物中正构烷烃及其同位素组成。结果显示了不同生物中正构烷烃碳数分布范围在C1 5~C33之间,呈单峰型分布;主峰碳数是水生生物(除海韭菜外)相对较低,主要为C23和C25,陆生木本植物次之,为C27;陆生草本植物较高,为C27和C29;CPI值分布在4.0~29.7之间;ACL值为26.0~29.6,分布与植物类型有关。青海湖水生生物中正构烷烃氢同位素组成分布在-209.8‰~-85.6‰之间,平均值为-169.2‰~-121.2‰;陆生植物的正构烷烃δD值为-196.7‰~-84.3‰之间,平均值为-173.0‰~-108.6‰。青海湖不同水生生物和不同陆生生物之间的正构烷烃氢同位素组成差别显著。研究发现,湖泊的含盐量对水生植物的正构烷烃氢同位素具有显著影响,环境湿度和降水量明显影响了陆生植物的正构烷烃氢同位素组成;植物的正构烷烃平均氢同位素组成随着其ACL值增加,具有变轻的趋势;不同种类植物的正构烷烃合成期间具有不同的氢同位素分馏效应,与陆生植物相比较,水生植物的正构烷烃相对于环境水更富集轻氢同位素,并且随着ACL值增加,环境水和正构烷烃之间的氢同位素分馏增大。  相似文献   

A Comparison Study on the δD Value of Polycyclic Aromatic Hydrocarbons in Hydrous Pyrolysate of Herbaceous Peat with Different Water Medium     

DUAN Yi  WU Yingzhong  XING Lantian  WU Yingqin  ZHAO Yang  LI Zhongping  MA Lanhu  DUAN Mingchen 《《地质学报》英文版》2023,97(6):1734-1743

To investigate the influence of diagenetic water media on the hydrogen isotopes of individual sedimentary aromatic compounds, a series of hydrous pyrolyses were conducted on herbaceous peat. Polycyclic aromatic hydrocarbons (PAHs) in hydrous pyrolysed samples and their hydrogen isotopic composition characteristics were studied. The aqueous medium demonstrated a significant influence on the hydrogen isotopic composition of the individual PAHs generated during pyrolysis. The results showed that the PAHs formed after pyrolysis in the presence of a saltwater medium with high δD value from a salt lake had a heavy hydrogen isotopic composition. The PAHs formed after pyrolysis in the presence of a fresh water medium with low δD value from a swamp had a light hydrogen isotopic composition. The difference in the average PAH δD value between the two hydrous experiments varied from –174‰ to –109‰, suggesting that the hydrogen isotopic composition of individual sedimentary PAHs can reflect the source of the diagenetic water medium. In addition, a comparative study found that the hydrogen isotopes of PAHs were superior to those of n-alkanes in the same sample for diagenetic water indications. The results indicated that the exchange of water-derived inorganic hydrogen and organic hydrogen was more intensive in freshwater experiments than in saltwater experiments. With an increase in the simulation temperature, the average δD value of PAHs generated in the hydrous simulation experiments showed an increasing trend, reflecting that the δD value of sedimentary PAHs formed with the participation of diagenetic water media was still closely related to the thermal maturity of organic matter. Comparative studies showed that the δD values of different types of organic compounds produced by hydrous pyrolysis of peat were in the order, PAHs > n-alkanes > methane.  相似文献   

贵州息烽温泉控热推覆构造的发现及成因研究     

张蕊  牟雨亮  朱立军  王甘露  曾波 《中国地质调查》2023,10(1):45-51

根据近年来磷矿深部勘探资料,对贵州息烽温泉的构造地质条件及地热特征开展研究,获得了有关温泉地质成因的新认识。①由洋水背斜、安清断层(F₁)和温泉断层(F₂)组成的叠瓦状逆冲推覆构造体系,构成了息烽温泉地热水系统的主体及边界,该控热构造体系内地表构造与地腹构造并不统一,老地层盖在新地层上,构成顶、底两层叠置的多个热储单元,这些热储单元是地热水形成和运移的良好场所。②安清断层(F₁)使多个热储单元直接接触,从而具有密切的水力联系,为导水、导热的良好通道; 温泉断层(F₂)构成了息烽温泉区地热水系统的边界。③大气降水沿断裂通道下渗至深部的碳酸盐岩热储层中,吸收热量形成地热水,在高温高压条件下,向洋水背斜核部进行迁移,受上覆寒武系碎屑岩盖层的保护和温泉断层的限制,形成洋水背斜西翼和北端的地热资源有利富集区,最后受分支断层阻挡而自然岀露。  相似文献   

陆地热泉钙华：重建古气候历史信息重要载体          下载免费PDF全文

杜磊  文华国  罗连超  董俊玲  温龙斌  游雅贤  王启宇 《中国地质》2022,49(3):802-821

【研究目的】陆地热泉钙华作为火山、地热区常见的陆相碳酸盐岩沉积物/岩被广泛用于恢复古环境,但其中可反映古气候信息的代用指标多受复杂外界条件变化控制,因此利用热泉钙华进行古气候信息提取有待深入研究。【研究方法】本文对当前热泉钙华在重建古气候信息方面的成功案例进行了总结,并梳理了与热泉钙华沉积相关的各类气候、非气候影响因素。【研究结果】研究认为针对热泉钙华进行古气候恢复代用指标的选取,目前较为可行的有C-O同位素、主微量元素,孢粉学数据由于孢粉保存的局限性,可作为佐证信息,配合其他气候代用指标来检验古气候意义的正确与否,同时需将热泉钙华中各项气候代用指标与生物地层学、冰芯、石笋等相对成熟的古气候研究手段进行对比,使各类古气候替代指标相互验证,从而更好的解读热泉钙华中古气候信息。【结论】利用热泉钙华中的各项气候代用指标进行可靠的古气候信息提取与恢复具有可行性。创新点：本文梳理了国内外热泉钙华恢复古气候的成功案例,并探讨了针对热泉钙华进行古气候恢复研究存在的问题。  相似文献   

滇东南都龙Sn-Zn多金属矿床交生硫化物微区主量元素、硫同位素特征及成因研究     

许赛华  任涛  白鑫  叶勤富  韩彬 《矿床地质》2022,41(4):741-750

都龙Sn-Zn多金属矿床位于滇东南老君山锡锌钨多金属成矿区南部,是中国3大锡石硫化物矿床之一。该矿床发育闪锌矿-黄铜矿-磁黄铁矿密切共生结构,即硫化物交生结构。文章利用电子探针和LA-MC-ICP-MS对具有交生结构的闪锌矿-黄铜矿-磁黄铁矿和毒砂进行了微区主量元素和硫同位素测试,以期明确其成因及硫的来源。主量元素测试结果显示,闪锌矿中的w(Zn)为52.23%~57.22%,w(S)为33.06%~36.10%,w(Fe)为9.92%~12.24%,w(Cu)为0.11%~0.30%;黄铜矿中的w(Cu)为33.95%~35.08%,w(S)为33.49%~35.27%,w(Fe)为30.74%~31.41%,w(Zn)为0.04%~1.50%;磁黄铁矿中的w(Fe)为49.30%~51.94%,w(S)为38.36%~39.69%,w(Zn)为9.35%~11.01%,w(Cu)为0.05%~0.15%。磁黄铁矿和黄铜矿包裹体边部和核部成分均一,且投影点全部落在固溶体出溶区域,说明都龙矿床交生闪锌矿-黄铜矿-磁黄铁矿是固溶体分离成因。原位S同位素分析结果显示,闪锌矿的δ³⁴S为0.9‰~3.2‰,磁黄铁矿的δ³⁴S为0.6‰~2.1‰,毒砂的δ³⁴S为2.9‰~4.2‰,黄铜矿的δ³⁴S为0.6‰~2.8‰,均显示为岩浆来源特征。主量元素温度计估算的闪锌矿-黄铜矿的形成温度介于285~394℃,指示该矿床主要硫化物形成于中高温阶段。  相似文献   

济南四大泉群水化学特征及其成因分析     

毛玉洁 《地质与勘探》2022,58(5):1042-1056

为明晰济南四大泉群水化学动态变化特征及成因,利用离子比例系数、PHREEQC模拟以及氢氧同位素反演等方法分析各泉群水化学成分特征及其形成过程。研究表明：（1）四大泉群阳离子Ca2+为优势离子,阴离子HCO3-为优势离子;（2）潭西泉和珍珠泉水化学类型稳定,而趵突泉和黑虎泉由HCO3—Ca型变为HCO3·SO4—Ca型;（3）四大泉群受地表水、寒武系凤山组-奥陶系岩溶水以及寒武系张夏组岩溶水混合补给,其中趵突泉、黑虎泉接受寒武系凤山组-奥陶系岩溶水补给占比略大,而潭西泉、珍珠泉接受寒武系张夏组岩溶水补给占比略大;黑虎泉滞留时间最短,循环交替强烈;（4）水岩相互作用强弱程度导致泉群水化学成分差异,溶解沉淀作用强度整体大于阳离子交换作用。趵突泉阳离子交换作用强度最弱,黑虎泉伴随有去白云化作用,潭西泉和珍珠泉水化学作用及强度类似,进一步印证潭西泉和珍珠泉有相同的补给来源及运移机制。该研究成果对水资源合理利用和岩溶大泉的保护具有重要意义。  相似文献   

前冬戴维斯海峡—巴芬湾区域海冰异常对中国东部春季极端降水频次的可能影响及预测价值     

张梦琪  孙建奇  郜永祺 《地学前缘》2022,29(5):401-409

本文研究了前期冬季北极海冰与中国东部春季极端降水频次的联系及其可能机制,并进一步探讨了海冰异常信号对极端降水的预测价值。结果表明,前冬戴维斯海峡—巴芬湾区域海冰异常与中国东部春季极端降水频次经验正交分解第一模态(EOF1)之间存在密切联系。当前冬戴维斯海峡—巴芬湾区域海冰异常偏多时,冬季大气环流呈现出类北大西洋涛动(NAO)正位相的异常分布,并伴随经向的北大西洋三极型海温异常。该海温异常可以从冬季持续到春季,进而激发出从北大西洋到欧亚中纬度的纬向遥相关波列,在东亚地区引起气旋型环流异常。该气旋型环流异常会引起中国东部地区湿度显著增加,上升运动增强,从而为该地区极端降水的发生提供了有利的背景条件。相反,当前冬戴维斯海峡—巴芬湾区域海冰异常偏少时,其滞后引起的春季环流异常则不利于中国东部地区极端降水的发生。进一步的交叉检验结果表明,前冬戴维斯海峡—巴芬湾区域海冰异常信号对中国东部春季极端降水具有重要的预测价值。  相似文献   

黄河三角洲浅层地下水盐分来源及咸化过程研究     

侯国华  高茂生  叶思源  赵广明 《地学前缘》2022,29(3):145-154

黄河三角洲地下水咸化已成为区域最突出的生态环境问题之一。识别地下水补给及盐分来源是有效控制和改善地下水咸化问题的关键。本研究采集了研究区浅层地下水、地表水和海水等不同类型水样,利用离子比、Piper三线图、吉布斯图等方法对八大离子浓度、δD和δ¹⁸O 组成、Br和Sr 浓度等进行地下水补给研究与盐分来源辨析。结果表明:(1)黄河三角洲浅层地下水以总溶解性固体(TDS)为338 g/L的咸水为主,地下水水化学类型较为单一,主要为Cl-Na型。(2)三角洲区域地下水以大气降水补给为主,并且在补给过程中经历了不同程度的蒸发作用的影响,黄河现行流路区域地下水主要来源于河水侧渗补给,但浅层地下水含水层水平渗透性较差限制了黄河侧渗补给范围。(3)海洋是黄河三角洲浅层地下水盐分的主要来源,黄河现行流路区域及近岸地下水盐分来源于海水混合,三角洲北部刁口河等古河道区域地下水盐分主要来源于海相蒸发盐淋滤溶解。  相似文献   

Origin,discovery, exploration and development status and prospect of global natural hydrogen under the background of “carbon neutrality”     

《China Geology》2022,5(4):722-733

Global energy structure is experiencing the third transition from fossil energy to non-fossil energy, to solve future energy problems, cope with climate change, and achieve net-zero emissions targets by 2050. Hydrogen is considered to be the most potential clean energy in this century under the background of carbon neutrality. At present, the industrial methods for producing hydrogen are mainly by steam-hydrocarbon (such as coal and natural gas) reforming and by electrolysis of water, while the exploration and development of natural hydrogen had just started. According to this literature review: (1) Natural hydrogen can be divided into three categories, including free hydrogen, hydrogen in inclusions and dissolved hydrogen; (2) natural hydrogen could be mainly from abiotic origins such as by deep-seated hydrogen generation, water-rock reaction or water radiolysis; (3) natural hydrogen is widely distributed and presents great potential, and the potential natural hydrogen sources excluding deep source of hydrogen is about (254±91)×10⁹ m³/a according to a latest estimate; (4) at present, natural hydrogen has been mined in Mali, and the exploration and development of natural hydrogen has also been carried out in Australia, Brazil, the United States and some European countries, to find many favorable areas and test some technical methods for natural hydrogen exploration. Natural hydrogen is expected to be an important part of hydrogen energy production in the future energy pattern. Based on a thorough literature review, this study introduced the origin, classification, and global discovery of natural hydrogen, as well as summarized the current global status and discussed the possibility of natural hydrogen exploration and development, aiming to provide reference for the future natural hydrogen exploration and development.©2022 China Geology Editorial Office.  相似文献   

三姑泉域水环境质量评价及水污染控制对策     

许志峰  张志祥  刘晓霞 《地下水》2012,(4):87-90

为确保三姑泉域水资源的可持续开发利用,采用常规方法对泉域水环境质量进行了评价。结果表明:三姑泉域的地表水和地下水已不同程度遭受污染,水环境的污染与煤矿开采以及工业废水和生活污水的不合理排放有关。结合当地实际提出水污染控制对策。研究成果为三姑泉域水资源管理和保护提供科学依据。  相似文献